Dinitrogen Activation by the Ti2N2 Molecule: A Matrix Isolation Study

作者：Manceron Laurent^*; Huebner Olaf; Himmel Hans Joerg

来源：European Journal of Inorganic Chemistry, 2009, 2009(5): 595-598.

DOI：10.1002/ejic.200801044

• Dinitrogen
• N-2 activation
• Bond activation
• Matrix isolation
• Titanium
• Nitrides

Herein we report on matrix isolation experiments carried out for the reaction of Ti-2(mu-N)(2) with N-2 in Ne and pure N-2 matrices. N-2 complexes with various degrees of N-2 activation are formed in the course of this reaction.

• 出版日期2009-2