Novel Synthesis of a New Surfactant 4-((4-Bromophenyl)(dodecyl)amino)-4-Oxobutanoic Acid Containing a Benzene Ring Using a Copper Catalyst Cross-Coupling Reaction and its Properties

作者：Chen, Minggui^*; Hu, Xinqi; Fu, Meilong

来源：Journal of Surfactants and Detergents, 2013, 16(4): 581-585.

DOI：10.1007/s11743-012-1423-3

• Surfactant with benzene ring
• Cross-coupling reaction
• Synthesis
• Property

A new surfactant 4-((4-bromophenyl)(dodecyl)amino)-4-oxobutanoic acid with a benzene spacer was synthesized via a novel copper catalyzed cross-coupling reaction. Its structure was confirmed by FTIR, H-1-NMR, C-13-NMR and HRMS; its purity was checked by HPLC. Dynamic light scattering and an atomic force microscope showed that it forms an unusual large-diameter premicellar aggregation below the CMC.

• 出版日期2013-7
• 单位长江大学; 西南石油大学