Diarylmethanols by catalyzed asymmetric aryl transfer reactions onto aldehydes using boronic acids as aryl source

作者：Schmidt Frank; Rudolph Jens; Bolm Carsten^*

来源：Advanced Synthesis & Catalysis, 2007, 349(4-5): 703-708.

DOI：10.1002/adsc.200600390

• arylboronic acids
• C-C bond formation
• diarylmethanols
• enantioselective catalysis
• organozinc reagents

Using a planar-chiral ferrocene as catalyst and combinations of functionalized aldchydes and substituted arylboronic acids as starting materials, asymmetric aryl transfer reactions give access to structurally diverse, optically active diarylinethanols in high yields and enantioselectivities.

• 出版日期2007-3