A hybrid compound based on octamolybdates and a rigid multidentate ligand: synthesis, structure and characterization

作者：Zhou, Shi^*; Liu, Bo; Chen, Ya-Guang; Li, Xiao-Min; Wang, Dong-Xiao

来源：RSC Advances, 2013, 3(47): 24910-24913.

DOI：10.1039/c3ra45917a

• HYDROTHERMAL SYNTHESIS
• CRYSTAL-STRUCTURE
• GAMMA-OCTAMOLYBDATE
• OPTICAL-PROPERTIES
• CLUSTERS
• COMPLEXES
• POLYMERS
• SUBUNITS
• SERIES

[Cu8L8(beta-Mo8O26)(gamma-Mo8O26)]center dot 3H(2)O, L = 2,4,5-tri(4-pyridyl)-imidazole, represents the first example with two types of 2D -> 2D parallel interpenetration frameworks, one has the (beta-Mo8O26)(4-) isomer, the other has the (gamma-Mo8O26)(4-) isomer. Furthermore, the two 2D networks in one 2D -> 2D parallel interpenetration framework are different, one is a CuL network, the other is a CuLMo8 network.

• 出版日期2013
• 单位东北师范大学; 吉林师范大学