Glancing angle deposited Ni nanopillars coated with conformal, thin layers of Pt by a novel electrodeposition: Application to the oxygen reduction reaction

作者：Xu Shuai; Wang Chao; Francis Sonja A; Tucker Ryan T; Sorge Jason B; Moghaddam Reza B; Brett Michael J; Bergens Steven H^*

来源：Electrochimica Acta, 2015, 151: 537-543.

DOI：10.1016/j.electacta.2014.11.028

• Ni-GLAD{Pt}
• platinum
• nickel
• oxygen reduction
• alkaline fuel cell

Glancing Angle Deposition (GLAD) was used to prepare 500 nm long Ni nanopillars directly on glassy carbon disc electrodes (Ni-GLAD/GC). Ni-GLAD{Pt}/GC core-layer nanopillars were prepared by depositing Pt on the Ni-GLAD substrate via a novel rotating disc electrode galvanostatic deposition, where a stationary blackened Pt counter electrode served as the Pt source. Scanning electron microscopy, cyclic voltammetry, and inductively-coupled mass spectrometry were employed to characterize the deposits. Results indicated that the Pt was deposited in a conformal manner on the Ni-GLAD giving a loading of 11.6 mu g. The Ni-GLAD{Pt}/GC electrode was ca. three fold more active than a {Pt}/GC (made with the same deposition in the absence of Ni) towards the oxygen reduction reaction (ORR) in 1.0 M KOH. As well, long term potentiostatic ORR studies showed the Ni-GLAD{Pt}/GC deposit was more durable than the {Pt}/GC, with the former completely retaining its initial performance after 5000 s polarization at 0.85 V vs. RHE, while {Pt}/GC lost 38% of its activity. Subsequent control experiments in the absence of O-2 showed that such decay was not due to loss of Pt over the prolonged ORR.

• 出版日期2015-1-1