科研之友
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摘要
An efficient palladium-catalyzed amination of aryl halides with amines, using rac-P-Phos as the ancillary ligand and Pd(OAc)(2) as the palladium source is developed. The ligand and all of the synthetic intermediates are stable to air and moisture, allowing the easy handling. The catalyst system performed well for a large number of different substrate combinations in 80-110 degrees C to furnish aromatic amines in high yields.
- 出版日期2009-7
- 单位复旦大学
