Activity coefficients at infinite dilution of organic solutes in the ionic liquid 1-ethyl-3-methylimidazolium trifluoromethanesulfonate using gas-liquid chromatography at T = (313.15, 323.15, and 333.15) K

作者：Olivier Eugene; Letcher Trevor M; Naidoo Paramespri; Ramjugernath Deresh^*

来源：Journal of Chemical Thermodynamics, 2010, 42(1): 78-83.

DOI：10.1016/j.jct.2009.07.010

• Activity coefficient at infinite dilution
• Ionic liquid
• 1-Ethyl-3-methylimidazolium trifluoromethanesulfonate

Activity coefficients at infinite dilution were determined for 24 solutes (n-alkanes, alk-1-enes, alk-1-ynes. cycloalkanes, alkylbenzenes, and alcohols) in the ionic liquid 1-ethyl-3-methylimidazolium trifluoromethanesulfonate by gas-liquid chromatography at three different temperatures T = (313.15, 323.15, 333.15) K. The partial molar excess enthalpy values at infinite dilution were calculated from the experimental results over the same temperature range. Selectivities and capacities at infinite dilution for the hexane/benzene and methanol/benzene separation problems were calculated from experimental infinite dilution activity coefficient values. The activity coefficients, enthalpies, selectivities, and capacities are discussed and compared to literature values for other ionic liquids, as well as industrial molecular solvents.

• 出版日期2010-1