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摘要
An efficient new ratiometric chemosensor, 6-imidazo-2-yl-5,6-dihydro-benzo[4,5]imidazo[1,2-c]-quinazoline (PB), which enables selective sensing of Al3+ in aqueous DMSO was synthesized by a facile one step condensation reaction of imidazole-2-carboxaldehyde with 2-(2-aminophenyl)-1H-benzimidazole. The probe PB was characterized by elemental analysis, H-1 and C-13 NMR, ESI-MS and IR spectral techniques. Upon addition of Al3+, the fluorescent probe PB induces ratiometric responses in both absorption and fluorescence spectra on the basis of a charge transfer mechanism. The receptor PB serves for highly selective, sensitive and ratiometric detection of Al3+ without the interference of biologically and environmentally relevant cations. The detection limit is found to be 5.3 x 10(-7) M. The Job's plot analysis indicates the binding stoichiometry of the complex to be 1 : 1 (host/guest).
- 出版日期2013
