科研之友
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摘要
Nitric oxide accounts for more than 95% of the total NOX emission from power plants, which is a major air pollutant. Therefore, it is imperative to accurately detect NO for environmental protection. A tripolar-electrode ionization sensor with a carbon nanotube (CNT) cathode is proposed for NO detection. The non-self-sustaining discharge state and the tripolar-electrode configuration ensures a long nanotube life, which ensures a good stability and fast response of the sensor. Experimental results demonstrate that the tripolar-electrode ionization sensor with 120 mu m separations has an intrinsic monotonously decreasing response to NO and exhibits a fast response time of 7 s and recovery time of 8 s. More consumption of the two metastable states N-2(A(3) Sigma u(+)) and N-2(a'(1) Sigma u(+)) of N-2 with the increasing of NO concentration is responsible for this. The tripolar-electrode ionization sensor also shows excellent long-term stability of at least one month due to the long CNT life. In addition, the weak effect of SO2 introduction on NO response indicates a good selectivity of the sensor to NO.
