A 3D photoluminescent cadmium(II)-organic framework with unusual pentanuclear cluster as secondary building unit

作者：Yang En Cui; Liang Qing Qing; Wang Peng; Zhao Xiao Jun^*

来源：Inorganic Chemistry Communications, 2009, 12(3): 211-213.

DOI：10.1016/j.inoche.2008.12.012

• Metal-organic framework
• Pentanuclear cluster
• 1,2,4-Triazole
• Secondary building unit

A crystalline 3D MOF with unique pentanuclear Cd(II)-cluster as SBU, [Cd(5)(H(2)O)(4)(ap)(3)(trz)(4)](n) (1) (H(2)aP = adipic acid, Htrz = 1,2,4-triazole), was isolated by hydrothermal method, which exhibits strong Htrz-based luminescent emission. More interestingly, ap ligands in 1 were observed to play the important roles for both the aggregate of polynuclear motif and the extension of the infinite 3D framework.

• 出版日期2009-3
• 单位天津师范大学