Assembly of an eight connected porous Cd(II) framework with octahedral and cubo-octahedral cages: Sorption and luminescent properties

作者：Tomar Kapil^*

来源：Inorganic Chemistry Communications, 2013, 37: 127-131.

DOI：10.1016/j.inoche.2013.09.065

• Hydrothermal
• Cadmium(II)
• Metal-organic framework
• Sorption
• Luminescence

An eight connected 3D porous coordination polymer, ([Cd(BTC)(0.66)(BPz)(2)]center dot 6H(2)O)(n) (1) (BTC = benzene-1,3,5-tricarboxylic acid, BPz = 3,3',5,5'-tetramethyl-4,4'-bipyrazole) has been synthesized from hydrothermal reaction of Cd(NO3)(2)center dot 4H(2)O with BPz and BTC. Complex 1 is a thermally stable microporous MOF having cubo-octahedral and octahedral cages as the Supermolecular Building Block (SBB) with an eight connected reo topology. It shows moderate N-2 sorption (101 cm(3) g(-1)) at 77 K with a BET surface area of 330 m(2) g(-1). Complex 1 also exhibits photoluminescent property in solid state with lambda(max) at 397 nm.

• 出版日期2013-11