The Impact of Loading and Temperature on the Oxygen Reduction Reaction at Nitrogen-doped Carbon Nanotubes in Alkaline Medium

作者：Wong W Y^*; Daud W R W; Mohamad A B; Kadhum A A H; Loh K S; Majlan E H; Lim K L

来源：Electrochimica Acta, 2014, 129: 47-54.

DOI：10.1016/j.electacta.2014.02.084

• metal-free catalyst
• nitrogen-doped carbon nanotubes
• oxygen reduction reaction
• catalytic effect

Metal-free nitrogen-doped carbon nanotube (NCNT) catalysts were synthesised via chemical vapour deposition with ethylenediamine and iron phthalocyanine. The electrochemically active NCNT was studied via thin-film rotating-ring disk voltamogram analysis to elucidate the optimum loading of catalysts for oxygen reduction reaction (ORR) in 0.1 M KOH electrolyte. In this study, the activity and stability of NCNT at elevated temperature were investigated. The current limiting plateau was achieved with loading above 500 mu g/cm(2) on glassy carbon tip with insignificant change in onset potential (c.a. +0.9 V vs RHE). The highest electron transfer number of 3.90 was obtained and it was found comparable to n = 3.95 on 130 mu g/cm(2) Pt/C catalysts. The subjection to cell's temperature from 298K to 343 K showed improved activity and was found stable above 323 K.

• 出版日期2014-5-20