Minimising reversion, using seawater and magnesium chloride, caused by the dissolution of tricalcium aluminate hexahydrate

作者：Palmer Sara J; Frost Ray L^*; Smith Matthew K

来源：Journal of Colloid and Interface Science, 2011, 353(2): 398-405.

DOI：10.1016/j.jcis.2010.09.062

• Seawater neutralisation
• Red mud
• Reversion
• Tricalcium aluminate hexahydrate
• Hydrotalcite

The increase in pH and aluminium concentration after the neutralisation of bauxite refinery residues is commonly known as reversion. This investigation reports the extent of reversion in synthetic supernatant liquor and possible methods to reduce reversion. This work is based on bauxite refinery residues produced from alumina refineries, where reversion is a real life situation in neutralised refinery residues. Trcalcium aluminate hexahydrate, a common phase in bauxite refinery residues, has been found to cause reversion. It has been established that reductions in both pH and aluminium from the seawater neutralisation process are due to the formation of 'Bayer' hydrotalcite Mg7Al2(OH)18(CO32-, SO42-)center dot xH(2)O. This is the primary mechanism involved in the removal of aluminium from solution. Increasing the volume of seawater used for the neutralisation process minimises the extent of reversion for both synthetic supernatant liquor and red mud slurry. The addition of MgCl2 center dot 6H(2)O also showed a reduction in reversion and confirmed that the decrease in aluminium and hydroxyl ions is due to the formation of Bayer hydrotalcite and not simply a dilution effect.

• 出版日期2011-1-15