科研之友
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摘要
Methyl and ethyl esters were prepared from lauric acid under conventional heating and microwave irradiation to determine the best fatty acid esterification conditions. These conditions were then applied in the conversion of trap grease (brown grease) to biodiesel. The trap grease is a potential feedstock for biodiesel production, due to its low cost and easy esterification. In this paper, trap grease catalytic esterification with methanol was performed under conventional heating and microwave irradiation. It was possible to obtain high conversions with conventional heating, but under microwave heating, the esterification reaction equilibrium was attained much faster. The trap grease biodiesel obtained from microwave assisted reactions showed a high conversion (96%) even at mild reaction conditions (trap grease: methanol molar ratio 1:6, 1.0% H2SO4, 393 K, 10 minutes). While these initial experiments were performed in a small-scale laboratory unit, the procedure could be easily scaled-up to a commercial continuous process.
- 出版日期2014-9
