Four Pentasaccharide Resin Glycosides from Argyreia acuta

作者:Yu, Bang-Wei; Sun, Jing-Jing; Pan, Jie-Tao; Wu, Xiu-Hong*; Yin, Yong-Qin*; Yan, You-Shao; Hu, Jia-Yan
来源:Molecules, 2017, 22(3): 440.
DOI:10.3390/molecules22030440

摘要

Four pentasaccharide resin glycosides, acutacoside F-I (1-4), were isolated from the aerial parts of Argyreia acuta. These compounds were characterized as a group of macrolactones of operculinic acid A, and their lactonization site of 11S-hydroxyhexadecanoic acid was esterified at the second saccharide moiety (Rhamnose) at C-2. The absolute configuration of the aglycone was S. Their structures were elucidated by established spectroscopic and chemical methods.