Novel supramolecular frameworks self-assembled from a two-dimensional polymeric network: Synthesis and crystal structure of a macrocyclic organotin(IV) complex

作者：Ma, CL^*; Han, YF; Zhang, RF; Wang, DQ

来源：European Journal of Inorganic Chemistry, 2005, (9): 1649-1652.

DOI：10.1002/ejic.200401056

• polymers
• self-assembly
• supramolecular chemistry
• tin

The two-dimensional polymer [nBu(2)Sn(O2CC6H4)](4) has been synthesized by the self-assembly of di-n-butyltin oxide and 4-carboxyphenylboronic acid. The X-ray crystal structure shows that the metal ions display a trigonal bipyramidal coordination geometry to bind the endocyclic oxygen atom. Intermolecular pi-pi stacking interactions between adjacent phenyl groups of the ligand cause the self-assembly into a 1D chain. In this chain one oxygen atom of the carboxylate group binds to one [nBu(2)Sn(O2CC6H4)](4) unit to give rise to a 2D architecture.

• 出版日期2005-5-6
• 单位聊城大学; 泰山学院