A luminescent Cu(I)-CN-1,2,4-triazolate open-framework with unique 2-fold interpenetrated (4,6)-connected fsc topology

作者：Feng, Yan-Ting; Li, Shu-Ni; Zhai, Quan-Guo^*; Jiang, Yu-Cheng; Hu, Man-Cheng

来源：Inorganic Chemistry Communications, 2013, 36: 150-154.

DOI：10.1016/j.inoche.2013.08.036

• CuCN
• 3,5-Bis(4-pyridyl)-1,2,4-triazole
• Open-framework
• Photoluminescence
• Topology

Self-assembly of CuCN, K3Fe(CN)(6) and 3,5-bis(4-pyridyl)-1,2,4-triazole (BPy-4Trz) ligand under hydrothermal conditions generated a novel hybrid crystalline compound, namely, {Cu-2(BPy-4Trz)(CN)}(n) (1). Two kinds of binuclear motifs, [Cu-2(Trz)(2)] and [Cu2CN], link each other through the 4-pyridyl and cyanide groups to give a three-dimensional (4,6)-connected open-framework of 1 with 2-fold interpenetrated fsc topology. The green fluorescence emissions are observed in the solid state at room temperature.

• 出版日期2013-10
• 单位陕西师范大学