A new Mo/S/Cu polymeric cluster: Synthesis, structure and properties

作者:Shu, Zunzhe; Wang, Chaohai; Li, Yao; Du, Haijuan; Niu, Yunyin*
来源:Main Group Chemistry, 2016, 15(1): 67-74.
DOI:10.3233/MGC-150184

摘要

Compound {[MoOS3Cu3Br(mu-bpy)(2.5)]center dot 0.75DMF}(8) is an isomorphous neutral 3D 4-fold interpenetrating architecture displaying self-interpenetrating feature. sometimes, the compound like the art. All of it have been characterized by single-crystal X-ray diffraction, elemental analysis, IR, TGA, and UV-vis. The results may provide fascinating insights into template effect on the construction of the cluster-based coordination polymers.