Two-dimensional pi-conjugated molecules based-on 2,6,9,10-tetra(prop-1-yn-1-yl)anthracene and their application to solution-processed photovoltaic cells

作者：Shin Jicheol; Kang Nam Su; Lee Tae Wan; Cho Min Ju; Hong Jae Min; Ju Byeong Kwon; Choi Dong Hoon^*

来源：Organic Electronics, 2014, 15(7): 1521-1530.

DOI：10.1016/j.orgel.2014.04.021

• Organic semiconductor
• Tetra(prop-1-yn-1-yl)anthracene
• Substitution position
• Thin film transistor
• Bulk heterojunction
• Photovoltaic cell

Novel two-dimensional p-conjugated molecules, i.e., 50,5000-((9,10-bis((4-hexylphenyl)ethynyl)anthracene-2,6-diyl)bis(ethyne-2,1-diyl))bis(5-hexyl-2,2'-bithiophene) (2,6-HBT) and 5',5 '''-((2,6-bis((4-hexylphenyl)ethynyl)anthracene-9,10-diyl)bis(ethyne-2,1-diyl))bis(5-hexyl-2,2'-bithiophene) (9,10-THB) were successfully synthesized and utilized as highly soluble p-type organic semiconductors for organic thin film transistors (TFTs) and solar cells. From the TFTs, the high hole mobility of the pristine film of 9,10-THB was measured to be 0.07 cm(2) V-1 s(-1) (I-on/off = 10(6)-10(7)), which is mainly attributed to slip-stacked charge-transport behavior in J-aggregation-induced crystallites. Further, a solution-processed solar cell made of 9,10-THB and PC61BM exhibited very promising and reproducible power conversion efficiencies of 3.30% and 2.53% with composition 1:1 and 1:2 w/w ratio, respectively.

• 出版日期2014-7