New symmetrically substituted 1,3,5-triazines as host compounds for channel-type inclusion formation

作者：Berger Ricarda; Hauser Juerg; Labat Gael; Weber Edwin; Hulliger Juerg^*

来源：CrystEngComm, 2012, 14(3): 768-770.

DOI：10.1039/c2ce06034e

A new synthetic procedure for the production of symmetrically substituted 1,3,5-triazines by cyclization from aromatic nitriles in the molten state with zinc chloride as a catalyst has been developed and applied for a number of aromatic and fluoro aromatic nitriles. The new triazine 8 [2,4,6-tris(40-bromobiphenylyl)-1,3,5-triazine] is shown to form channel-type inclusion compounds with several aromatic solvents, featuring two different channels in the same crystal.

• 出版日期2012