Nucleophilic displacement of ammonia from ammonia borane for the preparation of alkylamine-, pyridine- and phosphine-boranes

作者：Ramachandran P Veeraraghavan^*; Kulkarni Ameya S

来源：RSC Advances, 2014, 4(50): 26207-26210.

DOI：10.1039/c4ra03397c

A near quantitative and safe preparation of a series of aliphatic amine-and phosphine-boranes from ammonia borane (AB) in refluxing THF has been achieved by exploiting the volatility of ammonia. A one-pot preparation of lithium aminoborohydrides from AB has also been described.

• 出版日期2014