Stereoselective C-alkylation of an iron (II) dichloroclathrochelate via free-radical reactions with alcohols

作者：Vershinin Mikhail A; Burdukov Alexey B; Pervukhina Natalie V; Eltsov Ilia V; Voloshin Yan Z^*

来源：Inorganic Chemistry Communications, 2013, 30: 159-162.

DOI：10.1016/j.inoche.2013.02.007

• Macrocyclic compounds
• Iron complexes
• Clathrochelates
• Radical substitution
• X-ray crystallography
• NMR spectroscopy

Free-radical substitution of one of the two chlorine atoms of the tris-dioximate.iron(II) dichloroclathrochelate with ethanol and iso-propanol radicals proceeding with high regioselectivity at their a-carbon atoms afforded the monofunctionalized macrobicyclic products, which were characterized both in solution and in solid state by multinuclear one- and two-dimensional NMR spectroscopy and X-ray crystallography, respectively.

• 出版日期2013-4