Assessment of the Electronic Properties of P ligands Stemming from Secondary Phosphine Oxides

作者：Martin David^*; Moraleda Delphine; Achard Thierry; Giordano Laurent; Buono Gerard

来源：Chemistry - A European Journal, 2011, 17(45): 12729-12740.

DOI：10.1002/chem.201101663

• carbonyl ligands
• density functional calculations
• ligand effects
• P ligands
• secondary phosphine oxides

We report the study of the net donating ability of monodentate and bidentate P ligands stemming from secondary phosphine oxides (SPOs). We experimentally measured and/or calculated the frequencies of CO stretching modes of various metal carbonyl complexes. The inferred electronic properties of the ligands span an unprecedented range, going from pi-accepting phosphite-like compounds, to extremely electron-donating ligands outclassing N-heterocyclic carbenes.

• 出版日期2011-11-4