A physics based reduced order aging model for lithium-ion cells with phase change

作者：Gambhire Priya; Hariharan Krishnan S^*; Khandelwal Ashish; Kolake Subramanya Mayya; Yeo Taejung; Doo Seokgwang

来源：Journal of Power Sources, 2014, 270: 281-291.

DOI：10.1016/j.jpowsour.2014.07.127

• Lithium ion cells
• Phase change electrodes
• Lithium iron phosphate
• Reduced order model

The electrochemical model has the potential to provide a robust and accurate battery management system, but is not the preferred choice as it involves solving non-linear, coupled partial differential equations. In the present work, a model order reduction of the complete electrochemical model for a lithium ion cell with phase change electrodes is carried out. The phase change phenomenon is described using a simple, concentration-dependent diffusivity derived from mixture rules. This reduced order model (ROM) is validated with experimental data from literature. The applicability of the model to capture the atypical behavior of the phase change electrode system is demonstrated. Using the cell response from ROM, charge discharge asymmetry and path dependence in a lithium iron phosphate (LFP) cell are explored in detail. In addition, side reaction kinetics and solid electrolyte interphase formation are included in the ROM framework to enhance its capability to predict cell aging. The model is used to investigate capacity losses occurring in a phase change electrode cell. Insights from these results are used to suggest cell operating guidelines for maximizing utilization.

• 出版日期2014-12-15