Development and physicochemical characterization of a new magnetic nanocomposite as an economic antibiotic remover

作者：Saygili Gulbahar Akkaya^*; Saygili Hasan; Koyuncu Filiz; Guzel Fuat

来源：Process Safety and Environmental Protection, 2015, 94: 441-451.

DOI：10.1016/j.psep.2014.10.005

• Nanoporous carbon
• Magnetic nanocomposite
• Tetracycline adsorption
• Tomato waste
• Regeneration
• Wastewater treatment

Maghemite (T-Fe2O3) nanoparticles were impregnated to nanoporous carbon obtained from tomato waste (TWNC). The prepared magnetic composite (MTWNC) was characterized and used to remove tetracycline (TC) from water and then easily be separated from the medium by a magnetic technique. The morphologies and surface chemistries of both magnetic and non-magnetic nanoporous carbons were studied by FTIR, XRD, SEM, SEM-EDX, VSM, BET surface area, proximate and elemental analysis determinations. Batch adsorption studies were carried out and the effects of pH, initial TC concentration, adsorbent dose, ionic strength and temperature were investigated. The adsorption kinetics of TC on MTWNC could be expressed well by the pseudo-second order model, and sorption isotherms were described by Langmuir equation with maximum adsorption capacity of 60.60 mg/g at pH 4 and 50 degrees C. Thermodynamic parameters showed that the adsorption of TC onto MTWNC was feasible, spontaneous and endothermic. Furthermore, the recyclability of the adsorbent was tested with 0.01M NaOH solution, and the results show that the synthesized composite adsorbent could be employed repeatedly in wastewater treatment.

• 出版日期2015-3