科研之友
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摘要
A series of bulky amine palladium complexes {[(Ar-NH2)(2)PdCl2]} were synthesized and characterized. The catalytic activity of the palladium complexes was evaluated via the direct C-H arylation of thiazoles with aryl bromides in aerobic conditions at 80-100 degrees C. Under the optimal conditions, 0.5-0.05 mol% of the bulky palladium complexes were found to be very efficient and produced the desired cross-coupling products in high yields.
- 出版日期2016-2-1
- 单位广东药科大学
