A Lanthanide-transition Metal Coordination Polymer:{[CuEu(Hbidc)_2(H_2O)_4]·H_2O}_n(H_3bidc=1H-benzimidazole-5,6-dicarboxylic Acid)

作者：ZHOU Xin Hui a b HUANG Wei a a b

来源：结构化学, 2011, (04): 496-501.

• 1H-benzimidazole-5
• 6-dicarboxylic acid
• 3d-4f
• heterometallic
• complex
• Cu+
• Eu3+

The title complex 1,{[CuEu(Hbidc)2(H2O)4]·H2O}n(H3bidc = 1H-benzimidazole-5,6-dicarboxylic acid),has been solvothermally synthesized and structurally characterized by single-crystal X-ray diffraction.Complex 1 crystallizes in triclinic,space group P1,with a = 7.791(2),b = 12.058(3),c = 12.109(3),α = 82.189(5),β = 72.407(5),γ = 89.184(4)°,V = 1073.7(5)3,C18H18CuEuN4O13,Mr = 713.86,Dc = 2.208 g/cm3,μ(MoKα) = 3.967 mm-1,F(000) = 700,GOOF = 0.950,Z = 2,the final R = 0.0531 and wR = 0.1068 for I > 2σ(I).Complex 1 possess a tape-like chain structure consisting of Eu2C8O4 and Cu2Eu2C18N4O4 metallic rings alternatively arranged and is the first 3d-4f heterometallic complex based on the 1H-ben-zimidazole-5,6-dicarboxylato ligand(Hbidc).Plenty of hydrogen-bonding and π...π stacking interactions connect the 1D chains to construct a 3D supramolecular architecture.

• 出版日期2011-4-15
• 单位南京邮电大学