Application of Ionic Liquid-Graphene-NiO Hollowsphere Composite Modified Electrode for Electrochemical Investigation on Hemoglobin and Electrocatalysis to Trichloroacetic Acid

作者：Zhao, Wenshu; Li, Xiaoyan; Wen, Zuorui; Niu, Xueliang; Shen, Qingfeng; Sun, Zhaolan; Dong, Ruixia; Sun, Wei^*

来源：International Journal of Electrochemical Science, 2017, 12(5): 4025-4034.

DOI：10.20964/2017.05.06

• NiO hollowsphere
• Direct electrochemistry
• Hemoglobin
• Carbon ionic liquid electrode
• Trichloroacetic acid

In this present paper NiO hollowsphere was synthesized by a solvothermal method. Then it characterized by different methods including powder X-ray diffraction and scanning electron microscopy. NiO hollowsphere was further mixed with hemoglobin (Hb), ionic liquid and graphene (GR) to get a biocomposite, which was casted on carbon ionic liquid electrode. Spectroscopic data showed that Hb kept its native structure in the mixture. Direct electron transfer of Hb were investigated with a pair of well-defined quasi-reversible redox peaks appeared and the formal peak potential (E-0') was got at -0.341 V (vs. SCE). The Hb modified electrode showed excellent electrocatalysis to trichloroacetic acid (TCA) reduction. Under the selected conditions the currents had a good linear relationship with TCA concentration from 1.5 to 10.0 mmol L-1 and the detection limit was 0.5 mmol L-1 (3 sigma). This Hb based electrode exhibited good stability and reproducibility, which could be used for third-generation electrochemical biosensor.

• 出版日期2017-5
• 单位海南师范大学