A highly selective ratiometric chemosensor for Ni2+ in a quinoxaline matrix

作者:Goswami Shyamaprosad*; Chakraborty Shampa; Adak Mono Kumar; Halder Sandipan; Quah Ching Kheng; Fun Hoong Kun; Pakhira Bholanath; Sarkar Sabyasachi
来源:New Journal of Chemistry, 2014, 38(12): 6230-6235.
DOI:10.1039/c4nj01498g

摘要

The monohydrazone of quinoxaline aldehyde (HOQA) is found to be a ratiometric and colorimetric probe for Ni2+. HOQA shows a remarkable color change from colorless to yellow upon specific and selective binding to nickel that can be identified even by the naked eye. The cation recognition property of the receptor is monitored by UV-vis and H-1-NMR titrations and also by DFT (Density Functional Theory) and TD-DFT (Time Dependent Density Functional Theory) calculations.

  • 出版日期2014-12