Azobenzene chemosensor based on nitrogen chelator for the detection of Cu (II) ion in aqueous medium

作者：Hrishikesan Elango; Kannan Palaninathan^*

来源：Inorganic Chemistry Communications, 2013, 37: 21-25.

DOI：10.1016/j.inoche.2013.09.010

• Azo dye
• Chemosensor
• Copper (II) ion
• Internal charge transfer

A bis-pyridine unit containing azobenzene chemosensor for Cu2+ ion is designed and synthesized with good yield. The structure of the receptor I is determined by FT-IR, H-1 NMR, C-13 NMR, ESI-MS and single crystal XRD. The receptor I is constructed on the basis of internal charge transfer (ICT) mechanism with bis-pyridine unit acting as the binding part for Cu2+ ion. In solution, the proposed receptor I produces a cation induced 120 nm blue shift for Cu2+ ion from 457 nm to 337 nm with remarkable colour change from red to colourless. Whereas no significant colour change is observed upon addition of other metal ions in aqueous HEPES buffer (pH 7.0). Moreover, spectroscopic studies confirm the formation of 1:1 stoichiometry between the receptor I and Cu2+. ion with an association constant of ca. 1.45 x 10(6) M-1. The receptor I is highly specific to Cu2+ ions in aqueous solution attributed to the rational design of the molecular structure.

• 出版日期2013-11