An effective trigger for energy release of vinylheptafulvene-based solar heat batteries

作者:Cacciarini Martina*; Vlasceanu Alexandru; Jevric Martyn; Nielsen Mogens Brondsted
来源:Chemical Communications, 2017, 53(43): 5874-5877.
DOI:10.1039/c7cc01050h

摘要

Stoichiometric copper(I) tetrakis(acetonitrile) is found to activate the thermal ring-closure reaction of a series of high-energy vinyl-heptafulvene isomers to the corresponding low-energy and photoactive dihydroazulenes, allowing the release of energy upon request.

  • 出版日期2017-5-28