A smart approach to achieve an exceptionally high loading of metal nanoparticles supported by functionalized extended frameworks for efficient catalysis

作者：Gole Bappaditya; Sanyal Udishnu; Mukherjee Partha Sarathi^*

来源：Chemical communications, 2015, 51(23): 4872-4875.

DOI：10.1039/c4cc09228g

The problem associated with metal nanoparticle (NP) agglomeration when trying to achieve a high loading amount has been solved by a new method of functionalization of MOFs' pores with terminal alkyne moieties. The alkynophilicity of the Au3+ ions has been utilized successfully for an exceptionally high loading (similar to 50 wt%) of Au-NPs on supported functionalized MOFs.

• 出版日期2015