[U(Tp(Me2))(2)(bipy)](+): A Cationic Uranium(III) Complex with Single-Molecule-Magnet Behavior

作者：Antunes Maria A; Pereira Laura C J; Santos Isabel C; Mazzanti Marinella; Marcalo Joaquim; Almeida Manuel^*

来源：Inorganic Chemistry, 2011, 50(20): 9915-9917.

DOI：10.1021/ic200705p

The addition of 2,2'-biPyridine to [U(Tp(Me2))(2)I] (1) results in the displacement of the iodide and the formation of the cationic uranium(III) complex [U(Tp(Me2))(2),(bipy)]I (2). This compound was isolated as a dark-green solid in good yield and characterized by IR and NMR spectroscopies, and its molecular structure was determined by single-crystal X-ray diffraction. Studies of its magnetic properties revealed a frequency dependence of magnetization with a blocking temperature of 4.5 K and, at lower temperatures, a slow relaxation of magnetization with an energy barrier of 18.2 cm(-1), characteristic of single-molecule-magnet behavior.

• 出版日期2011-10-17
• 单位中国地震局