A beta-to-beta 2,5-thienylene-bridged cyclic porphyrin tetramer: its rational synthesis and 1:2 binding mode with C-60

作者:Song Jianxin; Aratani Naoki*; Shinokubo Hiroshi; Osuka Atsuhiro
来源:Chemical Science, 2011, 2(4): 748-751.
DOI:10.1039/c0sc00605j

摘要

A beta-to-beta 2,5-thienylene-bridged cyclic porphyrin tetramer was rationally synthesized via a concise synthetic route. The tetraporphyrin exhibits a positive cooperative binding ability to C-60 and demonstrates a new potential of the nonplanar, distorted cyclic porphyrin arrays.

  • 出版日期2011