A new mixed N-/O-donor for constructing functional Cu-II-coordination polymer: Crystal structure, photocatalysis and magnetic properties

作者：Guo, Sha-Sha; Wang, Zhong-Long; Xu, Guo-Wang; Wu, Ya-Pan; Li, Dong-Sheng^*

来源：Inorganic Chemistry Communications, 2014, 49: 143-146.

DOI：10.1016/j.inoche.2014.09.035

• Cu-II compound
• Crystal structure
• Photocatalytic activity
• Magnetic property

A first transition-metal coordination polymer [CuH2L(H(2)0)](n) (1) based on a new mixed N-/0-donors 5-[2-carboxy-3-(1H-tetrazol-5-yI)-phenoxy]-isophthalic acid (H4L), which exhibits a 2D 3-connected polymeric network, has been presented and characterized by single-crystal X-ray diffraction, elemental analysis, IR and TGA. It has prominently displayed highly photocatalytic degradation activity for dye degradation as well as antiferromagnetic interactions between the adjacent Cu-II ions.

• 出版日期2014-11
• 单位三峡大学