2-(1,1-dicyanomethylene)rhodanine A novel, efficient electron acceptor

作者：Insuasty Alberto; Ortiz Alejandro; Tigreros Alexis; Solarte Efrain; Insuasty Braulio^*; Martin Nazario

来源：Dyes and Pigments, 2011, 88(3): 385-390.

DOI：10.1016/j.dyepig.2010.08.011

• Donor
• Acceptor
• Push-Pull
• Rhodanine
• Dyes

The push-pull behaviour of novel 2-(11-dicyanomethylene)rhodanines bearing an electron donor N N-dimethylaniline or tetrathiafulvalene group on the C-5 of the heterocyclic ring was studied using experimental (electrochemical and spectroscopical analysis) and theoretical (DFT/B3LYP/631G*) methods Calculations showed a remarkable push pull trend with the HOMO mainly located on the donor moiety and the LUMO on the acceptor dicyanom

• 出版日期2011-3