A silver(I) coordination derivative of 2,3-dimethylthio-6-pyridyl tetrathiafulvalene, synthesis, crystal structure and electrochemical properties

作者：Liu Yu; Zhu Qin Yu; Dai Jie^*; Zhang Yong; Bian Guo Qing; Lu Wen

来源：Journal of Coordination Chemistry, 2007, 60(21): 2319-2326.

DOI：10.1080/00958970701261378

• tetrathiafulvalene
• silver complex
• crystal structure
• electrochemistry

A silver coordination compound [Ag(I)( DMT-TTF-py)(2)CH(3)CN] ClO(4) center dot CH(2)Cl(2) has been synthesized by reaction of DMT-TTF-py with AgClO(4). Structure analysis shows that the cations self-assemble to dimeric units through Ag center dot center dot center dot Ag interactions. Each silver(I) has a T-shaped AgN(3) coordination geometry. In the dimeric units, there are short C center dot center dot center dot S and C center dot center dot center dot C contacts between the two DMT-TTF-py molecules. The dimeric units are further assembled to a zigzag packing structure. The cyclic voltametric behavior of the ligand shows two-step reversible redox waves, which are shifted to lower values due to coordination to silver.

• 出版日期2007
• 单位南京大学; 苏州大学; 宿州学院