Facile synthesis of Mn-3[Co(CN)(6)](2)center dot nH(2)O nanocrystals for high-performance electrochemical energy storage devices

作者：Zhao, Qunxing; Zhao, Mingming; Qiu, Jiaqing; Pang, Huan^*; Lai, Wen-Yong^*; Huang, Wei^*

来源：Inorganic Chemistry Frontiers, 2017, 4(3): 442-449.

DOI：10.1039/c6qi00595k

• ALL-SOLID-STATE
• PRUSSIAN BLUE
• ASYMMETRIC SUPERCAPACITORS
• FLEXIBLE SUPERCAPACITORS
• MICRO-SUPERCAPACITORS
• ELECTRODE MATERIALS
• BATTERY ELECTRODES
• FRAMEWORK
• COMPOSITES
• CATHODE

Recently, although great efforts have been committed to enhance the electrochemical performance of supercapacitors (SCs), these devices are still unable to meet our expectations on account of limited working voltage, insufficient cycle life, low mechanical flexibility, and high cost. In this work, we have successfully synthesized several Mn-3[Co(CN)(6)](2)center dot nH(2)O nanocrystals by a mild precipitation method at room temperature. These Mn-3[Co(CN)(6)](2)center dot nH(2)O nanocrystals, as a novel kind of positive electrode materials, are firstly applied in flexible solid-state electrochemical energy storage devices. The best one of the asassembled devices based on the as-prepared Mn-3[Co(CN)(6)](2)center dot nH(2)O nanocrystals shows high electrochemical performance activity, which offers the highest volumetric energy density of 4.69 mW h cm(-3) at 10 mA cm(-2) and exhibits the largest power density of 177.1 mW cm(-3) at 20.0 mA cm(-2). Remarkably, the device displayed wonderful mechanical flexibility as the bending angle range from 0 degrees to 180 degrees. Moreover, the device demonstrated little capacitance change over 7000 cycles at 1.0 mA cm(-2), and exhibited a great cycling stability with 96.1% capacitance retention.

• 出版日期2017-3-1
• 单位南京工业大学; 扬州大学; 南京邮电大学