A 3D purely inorganic porous framework based on Keggin polyoxoanions

作者：Han, Xin-Bao; Zhang, Zhi-Ming^*; Wang, Zhi-Shu; Zhang, Huan; Duan, Hui; Wang, En-Bo

来源：Inorganic Chemistry Communications, 2012, 18: 47-49.

DOI：10.1016/j.inoche.2012.01.006

• Inorganic porous framework
• Keggin
• Polyoxometalate

A purely inorganic porous framework based on Keggin polyoxoanions K2NaH2[BW12O40]center dot 12H(2)O (1) has been prepared and characterized by single-crystal X-ray analysis, IR and XRD analysis. Compound I crystallized in a chiral space group P6(4)22 with hexagonal symmetry. In compound 1, the 3D inorganic porous framework possesses of the ID hexagon channels along the c axis. Furthermore, the porous framework exhibits reversible water sorption capability.

• 出版日期2012-4
• 单位东北师范大学