Dispersion of pristine single-walled carbon nanotubes in water by a thiolated organosilane: Application in supramolecular nanoassemblies

作者：Bottini Massimo^*; Magrini Andrea; Rosato Nicola; Bergamaschi Antonio; Mustelin Tomas

来源：Journal of Physical Chemistry B, 2006, 110(28): 13685-13688.

DOI：10.1021/jp062668r

We report a novel technique to disperse pristine single-walled carbon nanotubes in water by ultrasonication in the presence of a thiolated organosilane and subsequent ultracentrifugation. As revealed by the sharp features in the visible range of the absorption spectrum and by transmission electron microscopy, the collected supernatant fraction was composed of small bundles of nanotubes coated by a thin layer of organosilane molecules. We hypothesized and demonstrated that the organosilane adsorbed onto the nanotubes through the thiol group leaving the silane group extruding out. The pristine properties of the nanotubes and the versatile chemistry available for sol-gel materials make the reported dispersed nanotubes an excellent scaffold for the realization of supramolecular nanoassemblies suitable for different applications. As examples, we decorated them with silica nanobeads, by using a water-in-oil nanoemulsion system, and with gold nanoparticles, by a previous derivatization with a second layer of thiolated organosilane providing exposed thiol groups.

• 出版日期2006-7-20