Nitrogen-15 NMR Spectroscopy of Sugar Sensor with B-N Interaction as a Key Regulator of Colonmetric Signals

作者:Egawa Yuya*; Tanaka Yoshiyuki; Gotoh Ryota; Niina Satoshi; Kojima Yu; Shimomura Naoki; Nakagawa Hiroko; Seki Toshinobu; Anzai Jun ichi
来源:Chemistry Letters, 2010, 39(11): 1188-1189.
DOI:10.1246/cl.2010.1188

摘要

Nitrogen-15 NMR spectroscopy showed strongly upheld values of the chemical shift for one of the azo nitrogen atoms of a boronic-acid-appended azo dye this indicated the formation of a boron nitrogen (B-N) dative bond The B-N dative bond was cleaved by sugar addition

  • 出版日期2010-11-5