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摘要
We show a convenient decarboxylative aldol process using a scandium catalyst and a PYBOX ligand to generate a series of highly functionalized chiral alpha-hydroxy esters. The protocol tolerates a broad range of beta-keto acids with inactivated aromatic and aliphatic alpha-keto esters. The possible mechanism is rationalized.
- 出版日期2014-4-29
- 单位南京大学
