Unraveling the Nature of Charge Excitations in La2CuO4 with Momentum-Resolved Cu K-Edge Resonant Inelastic X-Ray Scattering

作者：Chen C C^*; Moritz B; Vernay F; Hancock J N; Johnston S; Jia C J; Chabot Couture G; Greven M; Elfimov I; Sawatzky G A; Devereaux T P

来源：Physical Review Letters, 2010, 105(17): 177401.

DOI：10.1103/PhysRevLett.105.177401

The results of model calculations using exact diagonalization reveal the orbital character of states associated with different Raman loss peaks in Cu K-edge resonant inelastic x-ray scattering (RIXS) from La2CuO4. The model includes electronic orbitals necessary to highlight the nonlocal Zhang-Rice singlet, charge transfer, and d-d excitations, as well as states with apical oxygen 2p(z) character. The dispersion of these excitations is discussed with prospects for resonant final state wave-function mapping. A good agreement with experiments emphasizes the substantial multiorbital character of RIXS profiles in the energy transfer range 1-6 eV.

• 出版日期2010-10-18