Adsorption of reactive yellow X-RG and reactive brilliant red X-3B onto cucurbit[8]uril and cucurbit[6]uril: Effect factors, adsorption behavior and mechanism study

作者：Li, Xiaolei; Xie, Xiaomei; Luo, Hanhan; Li, Lan; Li, Zhuang; Xue, Zhiyong^*; Li, Wei^*

来源：Journal of Colloid and Interface Science, 2017, 498: 31-46.

DOI：10.1016/j.jcis.2017.03.043

• Cucurbiturils
• Adsorption
• Dye
• Mechanism

Cucurbit[8]uril (CB[8]) and cucurbit[6]uril (CB[6]) were applied as a high efficiency absorbent to remove reactive yellow X-RG and reactive brilliant red X-3B dyes in aqueous solution. Factors affecting adsorption such as dosage, contact time, temperature, pH value and metal cation were investigated. The adsorption isotherms for X-RG followed the Langmuir and Sips model while for X-3B followed the Freundlich model. Adsorption thermodynamic showed that X-RG and X-3B adsorption onto CB[8] and CB[6] was a spontaneous and enthalpy-driven process. Adsorption kinetics was determined to follow the pseudo second -order model. In order to examine the adsorption mechanism, adsorbents and adsorption products of cucurbiturils were characterized further by several physicochemical techniques. FT-IR, TG analyses and DFT calculations revealed the formation of the new inclusion complexes, and Zeta potentials reveals the electrostatic interaction may be the significant driven force. UV-vis adsorption spectra were investigated by TDDFT and results showed that the main absorption bands of X-RG and X-3B mainly arisen from pi -> pi* and n -> pi* transition. Encapsulated with CBn, the UV-vis absorption bands of inclusion complexes were shifted by 10-15 nm due to intermolecular charge transfer (ICT).

• 出版日期2017-7-15
• 单位武汉纺织大学