Nanoscale insight into the exfoliation mechanism of graphene with organic dyes: effect of charge, dipole and molecular structure

作者：Schlierf Andrea; Yang Huafeng; Gebremedhn Elias; Treossi Emanuele; Ortolani Luca; Chen Liping; Minoia Andrea; Morandi Vittorio; Samori Paolo^*; Casiraghi Cinzia; Beljonne David; Palermo Vincenzo

来源：Nanoscale, 2013, 5(10): 4205-4216.

DOI：10.1039/c3nr00258f

We study the mechanism of surface adsorption of organic dyes on graphene, and successive exfoliation in water of these dye-functionalized graphene sheets. A systematic, comparative study is performed on pyrenes functionalized with an increasing number of sulfonic groups. By combining experimental and modeling investigations, we find an unambiguous correlation between the graphene-dye interaction energy, the molecular structure and the amount of graphene flakes solubilized. The results obtained indicate that the molecular dipole is not important per se, but because it facilitates adsorption on graphene by a %26quot;sliding%26quot; mechanism of the molecule into the solvent layer, facilitating the lateral displacement of the water molecules collocated between the aromatic cores of the dye and graphene. While a large dipole and molecular asymmetry promote the adsorption of the molecule on graphene, the stability and pH response of the suspensions obtained depend on colloidal stabilization, with no significant influence of molecular charging and dipole.

• 出版日期2013