A new, three-component cobalt-catalysed domino reaction leading to ferrocenyl-tetrahydro-4(1H)-pyrimidinone derivatives

作者:Balogh Janos; Csok Zsolt; Parkanyi Laszlo; Ungvary Ferenc; Kollar Laszlo; Skoda Foeldes Rita*
来源:Journal of Organometallic Chemistry, 2012, 718: 131-138.
DOI:10.1016/j.jorganchem.2012.08.009

摘要

The use of N-(alkyl/arylmethyl)-ferrocenylimines as ketene scavengers in the cobalt-catalysed carbonylation of ethyl diazoacetate resulted in the formation of tetrahydro-4(1H)-pyrimidinones as the main products. The structures of the new compounds were determined by various NMR techniques including 2D measurements. In some cases, the stereochemistry was proved by X-ray crystallography.

  • 出版日期2012-11-1