Novel Bi/BiOBr/AgBr composite microspheres: Ion exchange synthesis and photocatalytic performance

作者：Lyu, Jianchang; Li, Zhenlu; Ge, Ming^*

来源：Solid State Sciences, 2018, 80: 101-109.

DOI：10.1016/j.solidstatesciences.2018.04.004

• Bi/BiOBr/AgBr microspheres
• Ion exchange
• Photocatalysis
• Visible light
• Mechanism

Novel Bi/BiOBr/AgBr composite microspheres were prepared by a rational in situ ion exchange reaction between Bi/BiOBr microspheres and AgNO3 . The characteristic of the as-obtained ternary microspheres was tested by X-ray diffraction (XRD), energy dispersive X-ray spectrometer (EDS), scanning electron microscope (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), UV-vis diffuse reflectance spectroscopy (UV-vis DRS) and photoluminescence (PL). Under visible light irradiation, Bi/BiOBr/AgBr microspheres exhibited an excellent photocatalytic efficiency for rhodamine B (RhB) degradation, which was about 1.4 and 4.9 times as high as that of Bi/BiOBr and BiOBr/AgBr, demonstrating that the highest separation efficiency of charge carriers in the heterostructured Bi/BiOBr/AgBr. The photocatalytic activity of Bi/BiOBr/AgBr microspheres just exhibited a slight decrease after three consecutive cycles. The photocatalytic mechanism investigation confirmed that the superoxide radicals (O-2(center dot)-) were the dominant reactive oxygen species for RhB degradation in Bi/BiOBr/AgBr suspension.

• 出版日期2018-6
• 单位中国科学技术大学