Finite element modelling of the oxidation kinetics of Zircaloy-4 with a controlled metal-oxide interface and the influence of growth stress

作者：Zumpicchiat Guillaume; Pascal Serge; Tupin Marc; Berdin Meric Clotilde

来源：Corrosion Science, 2015, 100: 209-221.

DOI：10.1016/j.corsci.2015.07.024

• Oxidation kinetics
• Zirconium alloys
• Finite element modelling
• Growth stress

Experimentally, zirconium-based alloys oxidation kinetics is sub-parabolic, by contrast with the Wagner theory which predicts a parabolic kinetics.
Two finite element models have been developed to simulate this phenomenon: the diffuse interface model and the sharp interface model. Both simulate parabolic oxidation kinetics.
The growth stress effects on oxygen diffusion are studied to try to explain the gap between theory and experience. Taking into account the influence of the hydrostatic stress and its gradient into the oxygen flux expression, sub-parabolic oxidation kinetics have been simulated. The sub-parabolic behaviour of the oxidation kinetics can be explained by a non-uniform compressive stress level into the oxide layer.

• 出版日期2015-11
• 单位中国地震局