A Neutral Dinuclear Silver(I) 4'-Phenyl-Terpyridine Compound

作者：Huang, Y.; Wang, Q.; Ma, Z.^*

来源：Journal of Structural Chemistry, 2018, 59(1): 182-187.

DOI：10.1134/S0022476618010286

• silver compound
• 4 '-phenyl-terpyridine
• thermal synthesis
• X-ray diffraction

A hydrothermal reaction between 4'-phenyl-terpyridine (L), silver(I) salt (silver nitrate), and disodium terephthalate led to the formation of the [Ag-2(mu(2)-OCOC6H4OCO)L-2] complex. Its structure is determined by single crystal X-ray diffraction and confirmed by H-1 NMR and IR. The compound features a dinuclear neutral {Ag-2(mu(2)-OCOC6H4OCO)} core in which each Ag+ ion is coordinated by three nitrogen atoms from the terpyridine ligand and one oxygen atom from the carboxylic group of terephthalate, forming an irregular AgN3O square coordination geometry with a separation of 11.3301(5) between the two silver ions.

• 出版日期2018-1
• 单位广西大学