A novel 4(4).6(6) 5-connected metal-organic framework with strong fluorescent emission constructed by m-thioacetatebenzoic acid

作者：Zhan Cai Hong; Feng Yun Long^*

来源：Journal of Solid State Chemistry, 2010, 183(6): 1226-1230.

DOI：10.1016/j.jssc.2010.03.034

• m-Thioacetatebenzoic acid
• Crystal structure
• Helical chain
• Topology
• Luminescent property

A novel uninodal 5-connected metal-organic framework (MOF), [Cd2L2(4,4'-bipy)(3/2)(H2O)(2)](n) (H2L = m-thioacetatebenzoic acid and 4,4'-bipy=4,4'-bipyridine), was prepared under hydrothermal condition It features an unusual brick-wall shape layer by 4,4'-bipy, which consists of right- and left-handed helical chains arrayed alternatively and finally expands by L2- to a rare 5-connected nov (4(4) 6(6)) topology network. Photoluminesce

• 出版日期2010-6
• 单位浙江师范大学